10º Congresso Internacional de Corrosão
22º Concurso de Fotografia de Corrosão e Degradação de Materiais
39ª Exposição de Tecnologias para Prevenção e Controle da Corrosão.

08/07/2025 – 11/07/2025

CDI – Centro de Difusão Internacional – USP

Perspectives in the Development of Oxidation Resistant Alloys for Advanced Ultra Super Critical Thermal Power Plants

Global warming due to carbon dioxide emissions is a major threat facing humanity. Thermal power plants contribute significantly to the carbon dioxide emission. One way to reduce carbon dioxide emissions by thermal power plants is to increase the operating efficiency of boilers employed in thermal power plants. Towards this, coal-fired power plants employ supercritical (374 ℃ and 22.1 MPa) and ultra-supercritical (600 ℃ and 27 MPa) operating conditions for steam generation. Advanced ultra-supercritical (AUSC) power plants operating at 710 ℃ and 31 MPa can provide further increase in thermal efficiency. The rise in temperature pressure threatens materials’ stability due to creep and steam and gas oxidation. This requires detailed research on these topics. As part of the national mission project on the development of AUSC technology, our laboratory has undertaken steam oxidation studies under AUSC conditions. We built a test loop to simulate the temperature and pressure in an autoclave and studied nickel base super alloys such as 740H and 617 and austenitic stainless steels such as 304HCu and Sanicro 25. Complementary techniques were employed to understand the oxidation behavior of the alloys. The alloys 617, 740H, and Sanicro 25 showed significantly low oxidation kinetics due to the formation of inner Cr2O3 scales and outer (Mn,Fe,Ni)Cr2O4 spinels. On the contrary, 304HCu suffered severe oxidation as it suffered chromium volatilization and steep chromium depletion in the alloy oxide interface. This talk will bring out the interplay among the alloy chemistry, microstructure, and corrosivity of the steam to give a perspective for alloy development against AUSC steam oxidation.

Prof. V.S. Raja

Prof. VS. Raja is currently Emeritus Fellow in the Department of Metallurgical Engineering and Materials Science, Indian Institute of Technology Bombay, India. He has made pioneering contributions to corrosion education, research and mitigating industrial problems. His research interests span structureproperty-corrosion topics mostly focused on localized corrosion, environmentally assisted cracking of light metals, weld related corrosion, development of novel coating and advanced ultrasupercritical steam oxidation. Prof. Raja supervised over 35 doctoral and 123 masters’ students and published over 250 papers in peer reviewed journals and conference proceedings. Lead editor of the book Stress Corrosion Cracking: Theory and Practice and Co-author of the book “Corrosion Failure Analysis: Basics, Case Studies and Solutions”. He is editor of Corrosion Science, and Speciality Chief Editor of Frontiers in Metals and Alloys and served as Editor of Transactions of Indian Institute of Metals. He has been with Corrosion Science, Engineering and Technology and Materials, Werkstoffe Und Korrosion and Corrosion Reviews and Journal of Bio-and Tribo-Corrosion as editorial advisory member. He is recipient of several national and international awards including Mascot National Award of Electrochemical Society of India (2003), Meritorious Contribution Award, NACE International India Section,(2009), VASVIK Award for Industrial Research (2014), Prof. S.P. Shukhatme Excellence in Teaching Award, IIT Bombay (2016), IRCC Impactful Research Award, IIT Bombay (2016), Technical Achievement Award, NACE International, USA (2018) Prof. H.H. Mathur Award, Indian Institute of Technology Bombay (2023). Lifetime Achievement by NCCI, CECRI Karaikudi (2024). He was Institute Chair Professor from 2010 until his retirement. He is Fellows of NACE International, USA (2011), Indian Institute of Metals (2014), The Electrochemical Society of India (2017), ASM International (2024) and He is the President, International Corrosion Council (2024-27).